I am not surprised. This is an absolutely fascinating subject and normal people are roaming around reading all sorts of things without the filter of someone else at the keyboard.
What makes Carlson’s broadly named journal article interesting is that it is clearly concerned with the Younger Dryas Boundary Hypothesis. He expresses a desire to test it more closely by appropriately examining existing ice records for chemical signals of the event, refering frequently to another objective overview from Melott which I am trying to post as well.
Note Carlson’s paper was written after Surovell et al had supposedly dumped the last shovel of dirt on the body of the hypothesis. It is hard to keep a good theory down these days.
I can’t find a handy Melott paper, but here is good article on the publication just before Sid Perkins turned his back on the subject of the Younger Dryas Boudary:
By Sid Perkins
Web edition: March 30, 2010
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A new study cites spikes of ammonium in Greenland ice cores as evidence for a giant comet impact at the end of the last ice age, and suggests that the collision may have caused a brief, final cold snap before the climate warmed up for good.
In the April Geology, researchers describe finding chemical similarities in the cores between a layer corresponding to 1908, when a 50,000-metric-ton extraterrestrial object exploded over Tunguska, Siberia, and a deeper stratum dating to 12,900 years ago. They argue that the similarity is evidence that an object weighing as much as 50 billion metric tons triggered the Younger Dryas, a millennium-long cold spell that began just as the ice age was loosening its grip (SN: 6/2/07, p. 339).
Precipitation that fell on Greenland during the winter after Tunguska contains a strong, sharp spike in ammonium ions that can’t be explained by other sources such as wildfires sparked by the fiery explosion, says study coauthor Adrian Melott, a physicist of the University of Kansas in Lawrence.
The presence of ammonium suggests that the Tunguska object was most likely a comet, rather than asteroids or meteoroids, Melott says. Any object slung into the Earth’s atmosphere from space typically moves fast enough to heat the surrounding air to about 100,000° Celsius, says Melott, so hot the nitrogen in the air splits and links up with oxygen to form nitrates. And indeed, nitrates are found in snow around the Tunguska blast. But ammonium, found along with the nitrates, contains hydrogen that most likely came from an incoming object rich in water — like an icy comet.
More than a century after the impact, scientists are still debating what kind of object blew up over Tunguska in 1908. They also disagree about whether an impact or some other climate event caused the Younger Dryas at the end of the ice age. But the presence of ammonium in Greenland ice cores at both times is accepted.
“There’s a remarkable peak of ammonium ions in ice cores from Greenland at the beginning of the Younger Dryas,” comments Paul Mayewski, a glaciologist at the University of Maine in Orono who was not involved in the new study. The new findings are “a compelling argument that a major extraterrestrial impact occurred then,” he notes.
Whenever a comet strikes Earth’s atmosphere, it leaves behind a fingerprint of ammonium, the researchers propose. Immense heat and pressure in the shock wave spark the creation of ammonia, or NH3, from nitrogen in the air and hydrogen in the comet. Some of the ammonium, or NH4+, ions generated during subsequent reactions fall back to Earth in snow and are preserved in ice cores, where they linger as signs of the cataclysmic event.
Although an impact big enough to trigger the Younger Dryas would have generated around a million times more atmospheric ammonia than the Tunguska blast did, the concentrations of ammonium ions in the Greenland ice of that age aren’t high enough.
But the relative dearth of ammonium in the ice might simply be a result of how the ice cores were sampled, Melott and his colleagues contend. Samples taken from those ice cores are spaced, on average, about 3.5 years apart, and ammonia could have been cleansed from the atmosphere so quickly that most of the sharp spike might fall between samples.
Melott, A.L., et al. 2010. Cometary airbursts and atmospheric chemistry: Tunguska and a candidate Younger Dryas event. Geology 38(Apr.):355. DOI: 10.1130/G30508.1
Abstract available at [Go to]
1Department of Physics and Astronomy, University of Kansas, Lawrence, Kansas 66045, USA
2Department of Physics and Astronomy, Washburn University, Topeka, Kansas 66621, USA
3Department of Chemistry, University of Kansas, Lawrence, Kansas 66045, USA
We find agreement between models of atmospheric chemistry changes from ionization for the A.D. 1908 Tunguska (Siberia region, Russia) airburst event and nitrate enhancement in Greenland Ice Sheet Project 2 (GISP2H and GISP2) ice cores, plus an unexplained ammonium spike. We then consider a candidate cometary impact at the Younger Dryas onset (YD). The large estimated NOx production and O3 depletion are beyond accurate extrapolation, but the ice core peak is much lower, possibly because of insufficient sampling resolution. Ammonium and nitrate spikes in both Greenland Ice Core Project (GRIP) and GISP2 ice cores have been attributed to biomass burning at the onset of the YD. A similar result is well resolved in Tunguska ice core data, but that forest fire was far too small to account for this. Direct input of ammonia from a comet into the atmosphere is adequate for YD ice core data, but not for the Tunguska data. An analog of the Haber process with hydrogen contributed by cometary or surface water, atmospheric nitrogen, high pressures, and possibly catalytic iron from a comet could in principle produce ammonia, accounting for the peaks in both data sets.